A simple coumarin as a turn-on fluorescence sensor for Al(III) ions.

نویسندگان

  • Tianrong Li
  • Ran Fang
  • Baodui Wang
  • Yongliang Shao
  • Jian Liu
  • Shouting Zhang
  • Zhengyin Yang
چکیده

A simple Al(3+) sensor, 8-acetyl-7-hydroxy-4-methylcoumarin (AHMC), was synthesized. It can display an excellent fluorescence "turn-on" response to Al(3+) over other common metal ions in methanol-water media. Theoretical calculations have also been carried out to understand the configuration of the AHMC-Al complex and rationalize experimental absorption data.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

An amine/imine functionalized microporous MOF as a new fluorescent probe exhibiting selective sensing of Fe3+ and Al3+ over mixed metal ions

Nowadays metal-organic frameworks with multiple luminescent centers are very fascinating as multifunctional luminescent material because of their luminescence properties, which could be systematically tuned by deliberate use of organic ligands and metal ions. In this research, we explored a microporous mixed-ligand MOF for highly selective and sensitive detection of metal ions. A two-fold inter...

متن کامل

A differentially selective sensor with fluorescence turn-on response to Zn2+ and dual-mode ratiometric response to Al3+ in aqueous media.

A novel quinoline-coumarin (QC) fluoroionophore conjugated by means of a triazolyl-pyrrolidinyl linker exhibits differential dual selectivity for Zn(2+) and Al(3+) in mixed media. QC acts as a turn on fluorescence sensor for Zn(2+) while exhibiting overall ratiometric selectivity for Al(3+) in aqueous media. Moreover, QC exhibited preferential second mode of selectivity for Al(3+) as it ratiome...

متن کامل

A Peptoid-Based Fluorescent Sensor for Cyanide Detection.

Peptoids, N-substituted glycine oligomers, are versatile peptidomimetics with diverse biomedical applications. However, strategies to the development of novel fluorescent peptoids as chemical sensors have not been extensively explored, yet. Here, we synthesized a novel peptoid-based fluorescent probe in which a coumarin moiety was incorporated via copper(I)-catalyzed azide-alkyne cycloaddition ...

متن کامل

Al(III) Coated Wire Selective Electrode Based on 5-Bromo(salicylidene-2-aminothiophenol) Schiff Base as a New Ionophore

A new Al(III) selective membrane based on 5-bromo(salicylidene-2-amino thiophenol) as a neutral carrier in a poly(vinyl chloride) (PVC) matrix is coated on platinum wire to determine trace amounts of Al(III) ion in various samples. The sensor exhibits a good response for Al(III) ion over a wide concentration range of 5.20 × 10-7 to 1.00 × 10-2 M  with Nernstian slope of 19...

متن کامل

A novel diethyl 2-(9-fluorenyl) malonate functionlized SBA-15 for selective optical sensing of Iron

In this study, highly ordered mesoporous silica material (SBA-15) functionalized with Diethyl 2 - (9 -fluorenyl) malonate as a flourophore is reported. The anchoring of flourophores to the hydroxyl group on SBA-15 surface was done with post synthesis method. The obtained materials were characterized by small and wide angle X-ray diffraction, N2 adsorption–desorption, Fourier transform infrared ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Dalton transactions

دوره 43 7  شماره 

صفحات  -

تاریخ انتشار 2014